Reaktion #2204031

Reaktionsgleichung

sodium perchlorate

bis(dimethylamino)dichloromethane

→

bis(dimethylamino)chlorocarbenium perchlorate

Ausbeute 96.7%

Lösungsmittel

water

water

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturcooling
2. 2
   FiltrationThe residue is filtered off
3. 3
   Waschenwashed with 10 ml of ice-water
4. 4
   Sonstigesubsequently dried at 50° C. under reduced pressure (7.0 Pa)

Vorschrift

3.60 g of sodium perchlorate in 10 ml of water are added with stirring to a solution of 5.00 g (29.2 mmol) of bis(dimethylamino)dichloromethane in 20 ml of water. The reaction mixture is subsequently stirred for 1 hour with ice-cooling. The residue is filtered off and washed with 10 ml of ice-water and subsequently dried at 50° C. under reduced pressure (7.0 Pa), giving 6.64 g of bis(dimethylamino)chlorocarbenium perchlorate, corresponding to a yield of 94.0%.

Quelle