Reaktion #2186213

ord-cc63c51796cd4806aee31ec9555b7d61

Reaktionsgleichung

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl) sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene
→
CC(C)(C)c1ccc([S+](c2ccc(C(C)(C)C)cc2)c2ccc(C(C)(C)C)cc2)cc1.[Br-]
tris(4-tert-butylphenyl)sulfonium Bromide

Edukte

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl) sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene

Reagenzien

Keine

Lösungsmittel

O
water

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThe target compound was obtained
  2. 2
    Sonstigethe procedure of Synthesis Example 1 aside
  3. 3
    Sonstigein Synthesis Example 1
  4. 4
    Extraktionfor extraction

Vorschrift

The target compound was obtained by following the procedure of Synthesis Example 1 aside from using bis(4-tert-butylphenyl) sulfoxide instead of the diphenyl sulfoxide and 4-tert-butylbromobenzene instead of the chlorobenzene in Synthesis Example 1, and increasing the amount of water for extraction.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07569326B2uspto-grants-2009_08