Reaktion #218247

Reaktionsgleichung

cobalt sulfate

nickel sulfate

manganese sulfate

ammonium sulfate

sodium hydroxide

→

nickel-manganese-cobalt hydroxide

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigeobtained in the above-described Example 1
2. 2
   workup.ADDITIONwas poured
3. 3
   Temperaturwas maintained at 11.05±0.05
4. 4
   ExtraktionThe mother liquor in the reaction vessel was periodically extracted
5. 5
   Einengenthe slurry was concentrated until the final
6. 6
   Einengenslurry concentration
7. 7
   EinengenThe nickel concentration in the periodically extracted mother liquor from the reaction vessel
8. 8
   EinengenAfter the target slurry concentration
9. 9
   Sonstigehad been obtained
10. 10
    Filtrationfiltration and water washing

Vorschrift

In a 2-L (liter) reaction vessel, 1.8 L of the mother liquor obtained in the above-described Example 1 was poured, and agitated at 250 rpm while maintaining the internal temperature at 50±1° C. To this, while supplying an aqueous solution of metal sulfates containing 1.5 mol/L of nickel sulfate, 1.5 mol/L of manganese sulfate and 1.5 mol/L of cobalt sulfate at a flow rate of 0.4 L/hr; and simultaneously supplying a 1.5 mol/L aqueous solution of ammonium sulfate at a flow rate of 0.03 L/hr; an 18 mol/L aqueous solution of sodium hydroxide was continuously supplied so that the pH in the reaction vessel was maintained at 11.05±0.05. The mother liquor in the reaction vessel was periodically extracted, and the slurry was concentrated until the final slurry concentration became about 1000 g/L. The nickel concentration in the periodically extracted mother liquor from the reaction vessel was 22 ppm. After the target slurry concentration had been obtained, the slurry was aged at 50° C. for 5 hours, filtration and water washing were repeated to obtain coagulated particles of a co-precipitated nickel-manganese-cobalt hydroxide.

Quelle