Reaktion #2175475

Reaktionsgleichung

2,2-dimethyl-1,3-dioxolane

hexafluoropropene

→

4-(1,1,2,3,3,3-hexafluoropropyl)-1,3-dioxolane

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeExample 1 was prepared
2. 2
   SonstigeThe crude reaction material
3. 3
   workup.DISTILLATIONwas distilled

Vorschrift

Example 1 was prepared by combining 2,2-dimethyl-1,3-dioxolane (200 g, 1.96 moles, Fluka Chemie GmbH, Deisenhofen, Germany) and Luperox 575 (10 g, 0.041 moles) (Arkema, Oakville, Ontario, Canada) were combined in a 600 mL Parr reactor (Parr Instrument Co., Moline, Ill.). The reactor was warmed to 75° C. and hexafluoropropene (300 g, 2.0 moles) (MDA Manufacturing Inc., Decatur, Ala.) was added at a constant rate. The reactor was allowed to stir at this temperature for 16 h. The crude reaction material was distilled using a ten plate Oldershaw column to afford 4-(1,1,2,3,3,3-hexafluoropropyl)-1,3-dioxolane (boiling point (b.p.) of 144° C.).

Quelle