Reaktion #217145

ord-0a2235a08e124f5788330dc1819d3bb4

Reaktionsgleichung

CCCCCCCCON1C(C)(C)CC(OC(=O)NNC(=O)OC2CC(C)(C)N(OCCCCCCCC)C(C)(C)C2)CC1(C)C
bis(1-octyloxy-2,2,6,6-tetra-methylpiperidin-4-yl) hydrazine-1,2-dicarboxylate
CC(=O)O.CC(=O)O.Ic1ccccc1
iodobenzene diacetate
→
CCCCCCCCON1C(C)(C)CC(OC(=O)N=NC(=O)OC2CC(C)(C)N(OCCCCCCCC)C(C)(C)C2)CC1(C)C
title compound
CCCCCCCCON1C(C)(C)CC(OC(=O)N=NC(=O)OC2CC(C)(C)N(OCCCCCCCC)C(C)(C)C2)CC1(C)C
Bis(1-octyloxy-2,2,6,6-tetramethylpiperidin-4-yl) Azodicarboxylate

Edukte

CCCCCCCCON1C(C)(C)CC(OC(=O)NNC(=O)OC2CC(C)(C)N(OCCCCCCCC)C(C)(C)C2)CC1(C)C
bis(1-octyloxy-2,2,6,6-tetra-methylpiperidin-4-yl) hydrazine-1,2-dicarboxylate
CC(=O)O.CC(=O)O.Ic1ccccc1
iodobenzene diacetate

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

The procedure of Example 4 is repeated using 4.6 g of bis(1-octyloxy-2,2,6,6-tetra-methylpiperidin-4-yl) hydrazine-1,2-dicarboxylate and 2.3 g of iodobenzene diacetate to afford 3.3 gg of the title compound as a pale yellow oil. NMR, IR and mass spectra analyses are consistent with the desired structure.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05470980uspto-grants-1995_11