Reaktion #217084

ord-99313379c6d5489481226546473cd6d6

Reaktionsgleichung

CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.[Na+]
sodium 2,4,6-tris(dimethylaminomethyl)phenolate
O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Al+3]
aluminium nitrate
→
CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.[Al+3]
aluminium tris(2,4,6-tris(dimethylaminomethyl)phenolate)

Edukte

CN(C)Cc1cc(CN(C)C)c([O-])c(CN(C)C)c1.[Na+]
sodium 2,4,6-tris(dimethylaminomethyl)phenolate
O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Al+3]
aluminium nitrate

Reagenzien

Keine

Lösungsmittel

CCCCO
1-butanol

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Filtrationthe precipitated sodium nitrate is filtered off

Vorschrift

20 g (0.069 mol) of sodium 2,4,6-tris(dimethylaminomethyl)phenolate and 57.1 g of 1-butanol are placed in a 100 ml round-bottomed flask having a magnetic stirrer, and then 8.70 g (0.023 mol) of aluminium nitrate are added. The solution is stirred for 2 hours, and then the precipitated sodium nitrate is filtered off. A clear, brown 25% accelerator solution of aluminium tris(2,4,6-tris(dimethylaminomethyl)phenolate) in 1-butanol is obtained.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05470896uspto-grants-1995_11