Reaktion #214839

Reaktionsgleichung

diphenyliodonium chloride

fluoroboric acid

phosphorous acid

diphenyliodonium bisulfate

→

diphenyliodonium fluoroborate

Lösungsmittel

water

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigeis prepared by the addition of 60° C. of an aqueous solution
2. 2
   workup.ADDITIONcontaining 29.2 g
3. 3
   SonstigeThe silver halide that precipitates
4. 4
   Filtrationis filtered off
5. 5
   Einengenthe filtrate concentrated

Vorschrift

The aromatic iodonium complex salts may be prepared by metathesis of corresponding aromatic iodonium simple salts (such as, for example, the diphenyliodonium bisulfate) in accordance with the teachings of Beringer, et al., J. Am. Chem. Soc. 81, 342 (1959). Thus, for examples, the complex salt diphenyliodonium tetrafluoroborate is prepared by the addition of 60° C. of an aqueous solution containing 29.2 g. (150 millimoles) silver fluoroborate, 2 g. fluoroboric acid, and 0.5 g. phosphorous acid in about 30 ml. of water to a solution of 44 g. (139 millimoles) of diphenyliodonium chloride. The silver halide that precipitates is filtered off and the filtrate concentrated to yield diphenyliodonium fluoroborate which may be purified by recrystallization.

Quelle