Reaktion #214252

ord-c71981136930439f9fc57a6a9cfed018

Reaktionsgleichung

CCCCCC(=O)Cl
hexanoyl chloride
C#C
acetylene
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum chloride
→
CCCCCC(=O)C=CCl
1-chloro-1-octen-3-one
Ausbeute 94.0%

Edukte

CCCCCC(=O)Cl
hexanoyl chloride
C#C
acetylene
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum chloride

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThis compound is prepared

Vorschrift

This compound is prepared according to the procedure of Price and Pappalardo [C. C. Price and J. A. Pappalardo, Org. Syn, 32, 27 (1952)] from hexanoyl chloride, acetylene, and aluminum chloride in 94% yield, bp 51°-52° C. (0.1 mm); λ max 1680, 1595, 941 cm-1.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04254285uspto-grants-1981_03