Reaktion #2139247

Reaktionsgleichung

N-(1-methyl-2-imidazolidinylidene)-N'-phenylthiourea

methyliodide

→

methyl N-(1-methyl-2-imidazolidinylidene)-N'-phenylcarbamimidothioate hydroiodide

Ausbeute 85.0%

Lösungsmittel

acetone

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturis refluxed for 2.5 hours
2. 2
   SonstigeThe reaction mixture is evaporated in vacuo
3. 3
   Sonstigethe oil obtained
4. 4
   Sonstigeis crystallized from acetone-ether (1:1)

Vorschrift

A mixture of 22.0 g (0.094 mole) of N-(1-methyl-2-imidazolidinylidene)-N'-phenylthiourea and 14.9 g (0.105 mole) of methyliodide in 500 ml of acetone is refluxed for 2.5 hours. The reaction mixture is evaporated in vacuo and the oil obtained is crystallized from acetone-ether (1:1) to give 30 g (85%) of methyl N-(1-methyl-2-imidazolidinylidene)-N'-phenylcarbamimidothioate hydroiodide; m.p. 122°-126° C.

Quelle