Reaktion #2119683

ord-9653e8a615734987abe4909a75e0fb9e

Reaktionsgleichung

CC(=O)O[C@@H]1O[C@H](COC(=O)c2ccccc2)[C@@H](OC(=O)c2ccccc2)[C@H]1OC(=O)c1ccccc1
CC(=O)O[C@@H]1O[C@H]
Clc1ncnc2[nH]ccc12
Clc1ncnc2[nH]ccc12
→
O=C(OC[C@H]1OC(n2ccc3c(Cl)ncnc32)[C@H](OC(=O)c2ccccc2)[C@@H]1OC(=O)c1ccccc1)c1ccccc1
O=C(OC[C@H]1OC(n2ccc

Edukte

CC(=O)O[C@@H]1O[C@H](COC(=O)c2ccccc2)[C@@H](OC(=O)c2ccccc2)[C@H]1OC(=O)c1ccccc1
CC(=O)O[C@@H]1O[C@H](COC(=O)c2
Clc1ncnc2[nH]ccc12
Clc1ncnc2[nH]ccc12

Reagenzien

c1ccc(-c2c3ccccc3cc3ccccc23)cc1
9-Phenylanthracene
O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.[Bi+3]
Bi(OTf)3

Lösungsmittel

ClCCl
dichloromethane

Reaktionsbedingungen

Temperatur
60°CELSIUS

Quelle

DOI: 10.1038/s4155739k HTE dataset from Pfizer