Reaktion #2094172

ord-327b7e796eca4bf29ba4d23e2e15d3a7

Reaktionsgleichung

O=C(O)/C=C(\c1ccccc1)C(F)(F)F
O=C(O)/C=C(\c1ccccc1
→
O=C(O)CC(c1ccccc1)C(F)(F)F
O=C(O)CC(c1ccccc1)C(

Edukte

O=C(O)/C=C(\c1ccccc1)C(F)(F)F
O=C(O)/C=C(\c1ccccc1)C(F)(F)F

Reagenzien

C1=CCCC=CCC1.C1=CCCC=CCC1.F[B-](F)(F)F.[Rh+]
Rh(COD)2+BF4-
c1ccc(-c2c3ccccc3cc3ccccc23)cc1
9-Phenylanthracene
C1COCCN1
morpholine
c1ccc(P(c2ccccc2)c2ccccc2)cc1
P(Ph)3
CC1(C)O[C@H](CP(c2ccccc2)c2ccccc2)[C@@H](CP(c2ccccc2)c2ccccc2)O1
(S,S)-DIOP

Lösungsmittel

[2H]C(Cl)(Cl)Cl
CDCl3
O
H2O

Reaktionsbedingungen

Temperatur
25°CELSIUS

Quelle

DOI: 10.1038/s4155739k HTE dataset from Pfizer