Reaktion #2093592

ord-399a2a3231424f0783642d3b5089d5b7

Reaktionsgleichung

CC1=CCC(O[Si](C)(C)C(C)(C)C)=CC1
CC1=CCC(O[Si](C)(C)C
→
C[C@H]1CC=C(O[Si](C)(C)C(C)(C)C)CC1
C[C@H]1CC=C(O[Si](C)

Edukte

CC1=CCC(O[Si](C)(C)C(C)(C)C)=CC1
CC1=CCC(O[Si](C)(C)C(C)(C)C)=C

Reagenzien

C1=CCCC=CCC1.C1=CCCC=CCC1.[Cl][Ir].[Cl][Ir]
[Ir(COD)Cl]2
c1ccc(-c2c3ccccc3cc3ccccc23)cc1
9-Phenylanthracene
O=P([O-])([O-])[O-].[K+].[K+].[K+]
1M K3PO4(aq.)
O
water
CC1(C)O[C@H](CP(c2ccccc2)c2ccccc2)[C@@H](CP(c2ccccc2)c2ccccc2)O1
(S,S)-DIOP

Lösungsmittel

OCC(F)(F)F
a,a,a-Trifluorotoluene

Reaktionsbedingungen

Temperatur
25°CELSIUS

Quelle

DOI: 10.1038/s4155739k HTE dataset from Pfizer