Reaktion #2028926

ord-0e361772d189481b8e0b4651e20f9776

Reaktionsgleichung

CC(=O)[C@@H](O)[C@@H](O)[C@@H](O)CO
1-Deoxy L-psicose
CC(=O)[C@H](O)[C@@H](O)[C@@H](O)CO
1-deoxy L-fructose
O[C@H](CS)[C@@H](O)CS
DTE
→
C[C@@H](O)[C@@H](O)[C@@H](O)[C@@H](O)CO
1-deoxy L-allitol

Edukte

CC(=O)[C@@H](O)[C@@H](O)[C@@H](O)CO
1-Deoxy L-psicose
CC(=O)[C@H](O)[C@@H](O)[C@@H](O)CO
1-deoxy L-fructose
O[C@H](CS)[C@@H](O)CS
DTE

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

1-Deoxy L-psicose prepared via a reaction of 1-deoxy L-fructose with DTE was reduced to obtain 1-deoxy L-allitol, which was then oxidized microbially (IK7), to produce 6-deoxy D-psicose. 1-Deoxy D-psicose thus obtained reacted with DTE. The reaction conditions are as follows.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08389248B2uspto-grants-2013_03