Reaktion #2028920

ord-b8d61152588a4bdda47de79ca5c6fd32

Reaktionsgleichung

O=C(CO)[C@@H](O)[C@@H](O)[C@H](O)CO
D-tagatose
O=C[C@@H](O)[C@H](O)[C@H](O)CO
D-arabinose
C[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C=O
L-fucose
C[C@H](O)[C@@H](O)[C@@H](O)C(=O)CO
6-deoxy L-tagatose
→
C[C@H](O)[C@@H](O)[C@H](O)C(=O)CO
6-deoxy L-sorbose

Edukte

O=C(CO)[C@@H](O)[C@@H](O)[C@H](O)CO
D-tagatose
O=C[C@@H](O)[C@H](O)[C@H](O)CO
D-arabinose
C[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)C=O
L-fucose
C[C@H](O)[C@@H](O)[C@@H](O)C(=O)CO
6-deoxy L-tagatose

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

With D-arabinose isomerase, L-fucose (6-deoxy L-galactose) was isomerized to 6-deoxy L-tagatose, which was further epimerized with D-tagatose 3-epimerase, to produce 6-deoxy L-sorbose.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08389248B2uspto-grants-2013_03