Reaktion #1875690

ord-2a5ab8982e364511ad1f2a069c8b9e89

Reaktionsgleichung

[K+].[OH-]
KOH
CC(=O)c1ccc(Oc2ccc(Cl)cc2)cc1Cl
1-[2-chloro-4-(4-chloro-phenoxy)-phenyl]-ethanone
O=C(O)c1ccc2c(c1)nc(-c1ccc3nc(-c4cc(Br)ccc4O)ccc3c1)n2C1CCCCC1
Compound 354
O=C(O)c1ccc2c(c1)nc(-c1ccc3nc(-c4cc(Br)ccc4O)ccc3c1)n2C1CCCCC1
2-[2-(5-Bromo-2-hydroxy-phenyl)-quinolin-6-yl]-1-cyclohexyl-1H-benzoimidazole-5-carboxylic acid
O=C(O)c1ccc2c(c1)nc(-c1ccc3nc(-c4ccc(Oc5ccc(Cl)cc5)cc4Cl)ccc3c1)n2C1CCCCC1
title compound
Ausbeute 49.0%
O=C(O)c1ccc2c(c1)nc(-c1ccc3nc(-c4ccc(Oc5ccc(Cl)cc5)cc4Cl)ccc3c1)n2C1CCCCC1
2-{2-[2-chloro-4-(4-chloro-phenoxy)-phenyl]-quinolin-6-yl}-1-cyclohexyl-1H-benzoimidazole-5-carboxylic acid
Ausbeute 49.0%

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Following the procedure and workup for Compound 354, Compound 354e (100 mg, 0.256 mmol) was reacted with 1-[2-chloro-4-(4-chloro-phenoxy)-phenyl]-ethanone (0.256 mmol) in ethanol (2 mL) using 10% w/v KOH in ethanol (506 μL, 0.64 mmol) to produce the title compound (75 mg, 49% yield). MS: 608.17 (M+H+); HPLC Procedure B, retention time=8.44 min.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07511145B2uspto-grants-2009_03