Reaktion #1826219

ord-c06d1ac8b4de4a549338736f76b9503c

Reaktionsgleichung

CC(C)Oc1ccc(/C=C/C=C/CO)cc1
(E,E)-5-(4-isopropoxyphenyl)-2,4-pentadienol
→
CC(C)Oc1ccc(/C=C/C=C/C=O)cc1
(E,E)-5-(4-isopropoxyphenyl)-2,4-pentadienal
Ausbeute 99.0%

Edukte

CC(C)Oc1ccc(/C=C/C=C/CO)cc1
(E,E)-5-(4-isopropoxyphenyl)-2,4-pentadienol

Reagenzien

[Mn+4].[O-2].[O-2]
manganese dioxide

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

According to the same manner as that described in Reference Example 20, (E,E)-5-(4-isopropoxyphenyl)-2,4-pentadienol was oxidized with activated manganese dioxide to give (E,E)-5-(4-isopropoxyphenyl)-2,4-pentadienal as an oil (yield: 99%).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05965589uspto-grants-1999_10