Reaktion #1824307

ord-de8312e90bae472b9207d821aeb00d74

Reaktionsgleichung

CC(=O)[O-].CC(=O)[O-].[Cu+2]
copper(II) acetate
NCC(=O)O
glycine
→
NCC(=O)[O-].NCC(=O)[O-].[Cu+2]
copper(II) glycinate

Edukte

CC(=O)[O-].CC(=O)[O-].[Cu+2]
copper(II) acetate
NCC(=O)O
glycine

Reagenzien

Keine

Lösungsmittel

CO
methanol
CO
methanol

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.STIRRINGAfter stirring for 2 hours at a falling temperature
  2. 2
    Sonstigethe product precipitated
  3. 3
    Filtrationis filtered off
  4. 4
    Sonstigedried

Vorschrift

1.8 g (9.8 mmoles) of copper(II) acetate are dissolved in 100 ml of hot methanol and a solution of 1.5 g (20 mmoles) of glycine in 50 ml of methanol is added with stirring to the resulting solution. The solution turns cloudy under the effect of precipitated product. After stirring for 2 hours at a falling temperature, the product precipitated is filtered off and dried. Yield: 2.5 g (96% of the theoretical), Mp.:>210° C.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05961668uspto-grants-1999_10