Reaktion #1822

ord-3780dab8e7fc4abdb18faae656691afb

Reaktionsgleichung

O.OC[C@@H](O)[C@@H](O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O)[C@H](O)[C@@H](O)CO
lactitol monohydrate
O.O.OC[C@@H](O)[C@@H](O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O)[C@H](O)[C@@H](O)CO
lactitol dihydrate
→
OC[C@H]1O[C@@H](O[C@@H]2[C@@H](CO)O[C@](O)(CO)[C@H]2O)[C@H](O)[C@@H](O)[C@H]1O
lactitol

Edukte

O.OC[C@@H](O)[C@@H](O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O)[C@H](O)[C@@H](O)CO
lactitol monohydrate
O.O.OC[C@@H](O)[C@@H](O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O)[C@H](O)[C@@H](O)CO
lactitol dihydrate

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Examples XII-XXVII elucidate the conditions at which lactitol monohydrate and lactitol dihydrate, respectively, may be obtained from aqueous solutions of lactitol. In each instance 200 g lactitol dihydrate was used as the starting material which wasd dissolved in an amount of water varying from 40 g to 50 g at 100° C. Thereupon the solutions obtained were cooled to a temperature varying from 25° C. to 45° C. and seeded with 2 g monohydrate or 2 g dihydrate. The crystallization proper occurred at temperatures between 18° C. and 45° C.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05726303uspto-grants-1998_03