Reaktion #1770355

ord-a87cb3a263614e8f89cfa61ba6249847

Reaktionsgleichung

C[C@]1(/C=C/c2ccccn2)[C@H](C(=O)O)N2C(=O)C[C@H]2S1(=O)=O
(E)-(2S,3S,5R)-3-methyl-3-(2-pyridin-2-yl-vinyl)-4,4,7-trioxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2carboxylic acid
[Na]
sodium
→
C[C@]1(/C=C/c2ccccn2)[C@H](C(=O)O)N2C(=O)C[C@H]2S1(=O)=O.[Na]
Sodium (E)-(2S,3S,5R)-3-methyl-3-(2-pyridin-2-yl-vinyl)-4,4,7trioxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid

Edukte

C[C@]1(/C=C/c2ccccn2)[C@H](C(=O)O)N2C(=O)C[C@H]2S1(=O)=O
(E)-(2S,3S,5R)-3-methyl-3-(2-pyridin-2-yl-vinyl)-4,4,7-trioxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2carboxylic acid
[Na]
sodium

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

83 mg (0.17 mmol) of (E)-(2S,3S,5R)-3-methyl-3-(2-pyridin-2-yl-vinyl)-4,4,7-trioxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2carboxylic acid were converted into the corresponding sodium salt analogously to Example 10.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05637579uspto-grants-1997_06