Reaktion #170610

ord-8d0facc9aa774b63aa888a33096f6c3e

Reaktionsgleichung

COC(=O)c1ccc(OCc2conc2-c2ccc(F)cc2)nc1
6-[3-(4-fluoro-phenyl)-isoxazol-4-ylmethoxy]-nicotinic acid methyl ester
CC(N)CO
rac-2-amino-1-propanol
C[C@H](CO)NC(=O)c1ccc(OCc2conc2-c2ccc(F)cc2)nc1
title compound
Ausbeute 41.0%
C[C@H](CO)NC(=O)c1ccc(OCc2conc2-c2ccc(F)cc2)nc1
6-[3-(4-Fluoro-phenyl)-isoxazol-4-ylmethoxy]-N—((R)-2-hydroxy-1-methyl-ethyl)-nicotinamide
Ausbeute 41.0%

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

As described for example 325, 6-[3-(4-fluoro-phenyl)-isoxazol-4-ylmethoxy]-nicotinic acid methyl ester (60 mg, 0.18 mmol) was converted, using D-alaminol instead of rac-2-amino-1-propanol, to the title compound (28 mg, 41%) which was obtained as a white solid MS: m/e=372.1 [M+H]+.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08846719B2uspto-grants-2014_09