Reaktion #170520

ord-9a175fd3efd3471089dae63af69a45e3

Reaktionsgleichung

COC(=O)c1ccc(OCc2c(-c3ccccc3)noc2C)nc1
6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinic acid methyl ester
NCCCCCCO
6-amino-1-hexanol
Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)NCCCCCCO)cn1
title compound
Ausbeute 20.0%
Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)NCCCCCCO)cn1
N-(6-Hydroxy-hexyl)-6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinamide
Ausbeute 20.0%

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

As described for example 220, 6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinic acid methyl ester (180 mg, 0.55 mmol) was converted, using 6-amino-1-hexanol instead of 3-amino-1-propanol, to the title compound (45 mg, 20%) which was obtained as a white solid. MS: m/e=410.3 [M+H]+.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08846719B2uspto-grants-2014_09