Reaktion #167844

ord-0f90406051104b23876669b5eadb5fab

Reaktionsgleichung

C#CCOc1cccnc1C
2-methyl-3-(prop-2-ynyloxy)pyridine
CC(C)(C)C(=O)OCN=[N+]=[N-]
azidomethyl pivalate
c1cc(-n2cnnn2)ncc1OCc1cn[nH]n1
Intermediate 13
c1cc(-n2cnnn2)ncc1OCc1cn[nH]n1
5-((2H-1,2,3-triazol-4-yl)methoxy)-2-(1H -tetrazol-1-yl)pyridine
→
Cc1ncccc1OCc1cnnn1COC(=O)C(C)(C)C
title compound
Cc1ncccc1OCc1cnnn1COC(=O)C(C)(C)C
(5-((2-Methylpyridin-3-yloxy)methyl)-1H-1,2,3-triazol-1-yl)methyl pivalate

Edukte

C#CCOc1cccnc1C
2-methyl-3-(prop-2-ynyloxy)pyridine
CC(C)(C)C(=O)OCN=[N+]=[N-]
azidomethyl pivalate
c1cc(-n2cnnn2)ncc1OCc1cn[nH]n1
Intermediate 13
c1cc(-n2cnnn2)ncc1OCc1cn[nH]n1
5-((2H-1,2,3-triazol-4-yl)methoxy)-2-(1H -tetrazol-1-yl)pyridine

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

The title compound was synthesized using 2-methyl-3-(prop-2-ynyloxy)pyridine and azidomethyl pivalate in a manner similar as that described in Intermediate 13, Step 3.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US08846675B2uspto-grants-2014_09