Reaktion #1668943

ord-24147d16c7c24fdaa3f02b4d59d1a949

Reaktionsgleichung

[I-].[I-].[Sm+2]
samarium diiodide
CCC(C)c1ccc2ccc3cccnc3c2n1
2-(2-butyl)-1,10-phenanthroline
CCC(C)=O
2-butanone
→
CCC(C)c1ccc2ccc3ccc(C(C)(O)CC)nc3c2n1
title compound
CCC(C)c1ccc2ccc3ccc(C(C)(O)CC)nc3c2n1
2-[(1-methylpropyl)]-9-[(1-hydroxy-1-methylpropyl)]-1,10-phenanthroline

Edukte

[I-].[I-].[Sm+2]
samarium diiodide
CCC(C)c1ccc2ccc3cccnc3c2n1
2-(2-butyl)-1,10-phenanthroline
CCC(C)=O
2-butanone

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigeprepared

Vorschrift

The title compound is prepared by following the General Procedure I with samarium diiodide and 2-(2-butyl)-1,10-phenanthroline, prepared as described by Example 16, and 2-butanone.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06730788B1uspto-grants-2004_05