Reaktion #1668531

ord-2adf31bc69194ff4a825b785b6c2d381

Reaktionsgleichung

O=C(O)c1ccc2c(c1)OC(F)(F)O2
O=C(O)c1ccc2c(c1)OC(
CC(Cl)c1cccnc1
CC(Cl)c1cccnc1
→
CC(OC(=O)c1ccc2c(c1)OC(F)(F)O2)c1cccnc1
CC(OC(=O)c1ccc2c(c1)

Edukte

O=C(O)c1ccc2c(c1)OC(F)(F)O2
O=C(O)c1ccc2c(c1)OC(F)(F)O2
CC(Cl)c1cccnc1
CC(Cl)c1cccnc1

Reagenzien

O=C([O-])[O-].[Cs+].[Cs+]
cesium carbonate
[I-].[K+]
potassium iodide

Lösungsmittel

CN(C)C=O
dmf
CN(C)C=O
DMF
CN(C)C=O
DMF

Reaktionsbedingungen

Temperatur
70°CELSIUS

Aufarbeitung

  1. 1
    workup.ALIQUOT
  2. 2
    workup.ADDITIONDilution of the aliquot (2 uL) with DMSO (200 uL).

Quelle

DOI: 10.1016/j.chempr.2024.04.001Fig 7 data from Golden paper