Reaktion #1612704

Reaktionsgleichung

m-toluidine

tri(tert-butyl)phosphine

9-(3-bromophenyl)-9-phenylfluorene

sodium tert-butoxide

→

3 -methylphenyl-3-(9-phenyl-9H-fluoren-9-yl)phenylamine

Lösungsmittel

hexane

toluene

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeIn a 200 mL three-neck flask were put
2. 2
   Sonstigewas set to 60° C.

Vorschrift

In a 200 mL three-neck flask were put 3.2 g (8.1 mmol) of 9-(3-bromophenyl)-9-phenylfluorene and 2.3 g (24.1 mmol) of sodium tert-butoxide. The air in the flask was replaced with nitrogen. To this mixture were added 40.0 mL of toluene, 0.9 mL (8 3 mmol) of m-toluidine, and 0.2 mL of a 10% hexane solution of tri(tert-butyl)phosphine. The temperature of this mixture was set to 60° C., and 44.5 mg (0.1 mmol) of bis(dibenzylideneacetone)palladium(0) was added to the mixture.

Quelle