Reaktion #1577799

ord-e74fd2bba4794cc6a414fd0977a4bb83

Reaktionsgleichung

O=Cc1cccc(Br)c1
O=Cc1cccc(Br)c1
→
CC1(C)OB(c2ccc(Br)cc2C=O)OC1(C)C
CC1(C)OB(c2ccc(Br)cc
Ausbeute 87.0%

Edukte

O=Cc1cccc(Br)c1
O=Cc1cccc(Br)c1
CAS: 3132-99-8

Reagenzien

C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH
CAS: 12148-71-9
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)O
CAS: 73183-34-3
CC(C)(C)N
CC(C)(C)N
CAS: 75-64-9
Nc1cccc2cccnc12
Nc1cccc2cccnc12
CAS: 578-66-5
CC1(C)OBOC1(C)C
CC1(C)OBOC1(C)C
CAS: 25015-63-8

Lösungsmittel

C1CCOC1
C1CCOC1
CAS: 109-99-9

Reaktionsbedingungen

Temperatur
90°CELSIUS

Quelle

DOI: 10.1021/jacs.5b11683Borylation dataset from Roche