Reaktion #1577756

ord-ec380466fa7c475c9db8da329756d037

Reaktionsgleichung

N#Cc1cccc2[nH]ccc12
N#Cc1cccc2[nH]ccc12
→
CC1(C)OB(c2cc3c(C#N)ccc(B4OC(C)(C)C(C)(C)O4)c3[nH]2)OC1(C)C
CC1(C)OB(c2cc3c(C#N)
Ausbeute 92.0%

Edukte

N#Cc1cccc2[nH]ccc12
N#Cc1cccc2[nH]ccc12
CAS: 16136-52-0

Reagenzien

C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH
CAS: 12148-71-9
CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1
CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)
CAS: 72914-19-3
CC1(C)OBOC1(C)C
CC1(C)OBOC1(C)C
CAS: 25015-63-8

Lösungsmittel

CCCCCC
CCCCCC
CAS: 110-54-3

Reaktionsbedingungen

Temperatur
60°CELSIUS

Quelle

DOI: 10.1021/ja0631652Borylation dataset from Roche