Reaktion #1577609

ord-04960d6e779e4313ae5e098dc259e93c

Reaktionsgleichung

Cc1nc2ccccc2o1
Cc1nc2ccccc2o1
→
Cc1nc2cccc(B3OC(C)(C)C(C)(C)O3)c2o1
Cc1nc2cccc(B3OC(C)(C
Ausbeute 43.0%

Edukte

Cc1nc2ccccc2o1
Cc1nc2ccccc2o1
CAS: 95-21-6

Reagenzien

C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH2+].C[OH2+].[Ir].[Ir]
C1=CCCC=CCC1.C1=CCCC=CCC1.C[OH
CAS: 12148-71-9
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)O
CAS: 73183-34-3
CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1
CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)
CAS: 72914-19-3

Lösungsmittel

C1CCOC1
C1CCOC1
CAS: 109-99-9

Reaktionsbedingungen

Temperatur
25°CELSIUS

Quelle

DOI: 10.1021/ja412563eBorylation dataset from Roche