Reaktion #1577595

ord-23ce4aa5744d4b52a155df6225c301b4

Reaktionsgleichung

Clc1ccc2[nH]ccc2c1
Clc1ccc2[nH]ccc2c1
→
CC1(C)OB(c2cc(Cl)cc3cc[nH]c23)OC1(C)C
CC1(C)OB(c2cc(Cl)cc3
Ausbeute 64.0%

Edukte

Clc1ccc2[nH]ccc2c1
Clc1ccc2[nH]ccc2c1
CAS: 17422-32-1

Reagenzien

C1=CCCC=CCC1.C1=CCCC=CCC1.[Cl-].[Cl-].[Ir].[Ir]
C1=CCCC=CCC1.C1=CCCC=CCC1.[Cl-
CAS: 12112-67-3
CC1(C)OBOC1(C)C
CC1(C)OBOC1(C)C
CAS: 25015-63-8
CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1
CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)
CAS: 72914-19-3
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C
CC1(C)OB(B2OC(C)(C)C(C)(C)O2)O
CAS: 73183-34-3

Lösungsmittel

C1CCOC1
C1CCOC1
CAS: 109-99-9

Reaktionsbedingungen

Temperatur
80°CELSIUS

Quelle

DOI: 10.1021/ja1006405Borylation dataset from Roche