Reaktion #1563888

ord-46c5fcb07c94481a8e8f0d3a8d9e85a9

Reaktionsgleichung

COc1ccccc1NC(=O)c1c(N)cccc1Sc1ccc([N+](=O)[O-])cc1
2-amino-N-(2-methoxyphenyl)-6-(4-nitrophenyl-thio)benzamide
O=S(=O)(O)O
H2SO4
→
COc1ccccc1NC(=O)c1c(N)cccc1Sc1ccc([N+](=O)[O-])cc1.O=S(=O)(O)O
2-amino-N-(2-methoxyphenyl)-6-(4-nitrophenyl-thio)benzamide sulfate
Ausbeute 72.0%

Edukte

COc1ccccc1NC(=O)c1c(N)cccc1Sc1ccc([N+](=O)[O-])cc1
2-amino-N-(2-methoxyphenyl)-6-(4-nitrophenyl-thio)benzamide
O=S(=O)(O)O
H2SO4

Reagenzien

Keine

Lösungsmittel

CCOC(C)=O
EA

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    FiltrationThe reaction mixture was filtered
  2. 2
    Sonstigeto get White solid

Vorschrift

2-amino-N-(2-methoxyphenyl)-6-(4-nitrophenyl-thio)benzamide dissolved in EA, stirred at room temperature, while dropped H2SO4 into mixture till occurred to white solid. The reaction mixture was filtered to get White solid; 72% yield;

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US09402819B2uspto-grants-2016_08