Reaktion #1536599

ord-4179bd76816946e28def8f1f34dcee90

Reaktionsgleichung

CCOC1(C(C)(C)C)SSC=C1CC(C)(C)C
3ethoxy-3-t-butyl-4-neopentyl 1,2 dithiole
[O-][Cl+3]([O-])([O-])O
perchloric acid
O
water
→
CC(C)(C)Cc1c[s+]sc1C(C)(C)C.[O-][Cl+3]([O-])([O-])[O-]
4-neopentyl-3-tertiarybutyl 1,2 dithiolium perchlorate
Ausbeute 100.3%

Edukte

CCOC1(C(C)(C)C)SSC=C1CC(C)(C)C
3ethoxy-3-t-butyl-4-neopentyl 1,2 dithiole
[O-][Cl+3]([O-])([O-])O
perchloric acid
O
water

Reagenzien

Keine

Lösungsmittel

CCO
ethanol

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    Sonstigethe precipitate which formed
  2. 2
    Filtrationwas filtered off

Vorschrift

A sample of 11.4 grams of 3ethoxy-3-t-butyl-4-neopentyl 1,2 dithiole dissolved in 15 grams of ethanol was treated with 14 grams of 70% perchloric acid. To the mixture was added 100 grams of water and the precipitate which formed was filtered off. There was isolated 13.7 grams (100% of theory) of 4-neopentyl-3-tertiarybutyl 1,2 dithiolium perchlorate.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04190727uspto-grants-1980_02