Reaktion #1507475

ord-565a5de21273402ca3b2b091199d3602

Reaktionsgleichung

Cl.NCCS(=O)(=O)Cl
Tauryl chloride hydrochloride
Cl.NCCS(=O)(=O)Cl
Tauryl chloride hydrochloride
[N-]=[N+]=[N-].[Na+]
sodium azide
[N-]=[N+]=[N-].[Na+]
sodium azide
[Cl-].[Na+]
sodium chloride
→
Cl.[N-]=[N+]=NS(=O)(=O)CCN
taurylazide hydrochloride

Edukte

Cl.NCCS(=O)(=O)Cl
Tauryl chloride hydrochloride
Cl.NCCS(=O)(=O)Cl
Tauryl chloride hydrochloride
[N-]=[N+]=[N-].[Na+]
sodium azide
[N-]=[N+]=[N-].[Na+]
sodium azide
[Cl-].[Na+]
sodium chloride

Reagenzien

Keine

Lösungsmittel

O
water
O
water
O
water

Reaktionsbedingungen

Temperatur
5°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.STIRRINGthe reaction mixture was stirred for 15 min

Vorschrift

Tauryl chloride hydrochloride and sodium azide were reacted with one another in a ratio of 1:1 in water. For this purpose, the calculated stoichiometric amount of sodium azide was dissolved in water and the solution was cooled to 5° C. Tauryl chloride hydrochloride was added while stirring and the reaction mixture was stirred for 15 min. By stripping off the water, a solid mixture of crystalline sodium chloride and taurylazide hydrochloride was obtained.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05889183uspto-grants-1999_03