Reaktion #1503307

ord-ff3cb721bd8649839440063b815b25d6

Reaktionsgleichung

CCCCCC1CCC([C@H]2CO[C@H](COCc3ccccc3)OC2)CC1
trans-2-benzyloxymethyl-5-(4-pentylcyclohexyl)-1,3-dioxane
[H][H]
hydrogen
→
CCCCCC1CCC([C@H]2CO[C@H](CO)OC2)CC1
trans-[5-(4-pentylcyclohexyl)-1,3-dioxan-2-yl]methanol

Edukte

CCCCCC1CCC([C@H]2CO[C@H](COCc3ccccc3)OC2)CC1
trans-2-benzyloxymethyl-5-(4-pentylcyclohexyl)-1,3-dioxane
[H][H]
hydrogen

Reagenzien

[Pd]
Pd

Lösungsmittel

C1CCOC1
THF

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

A solution of 100 mmol of trans/trans-2-benzyloxymethyl-5-(4-pentylcyclohexyl)-1,3-dioxane is hydrogenated in 300 ml of THF with the addition of 2.0 g of 5% Pd/activated charcoal until the take-up of hydrogen is complete. trans/trans-[5-(4-pentylcyclohexyl)-1,3-dioxan-2-yl]methanol is obtained by conventional work-up.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05911912uspto-grants-1999_06