Reaktion #1483120

Reaktionsgleichung

2-(2-Hydroxyphenyl)-1,10-phenanthroline

2-(2-Hydroxyphenyl)-1,10-Phenanthroline

lithium t-butoxide

→

Lithium 2-(1,10-Phenanthrolin-2-yl)-Phenolate

Lösungsmittel

tetrahydrofuran

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.STIRRINGThe precipitated product was stirred at room temperature in the reaction mixture for 1 hour
2. 2
   Sonstigethe reaction
3. 3
   FiltrationThe lithium 2-(1,10-phenanthrolin-2-yl)-phenolate was filtered off
4. 4
   Waschenwashed well with diethyl ether
5. 5
   Sonstigeair-dried

Vorschrift

2-(2-Hydroxyphenyl)-1,10-phenanthroline (4) (20 g, 73.45 mMole) was dissolved in tetrahydrofuran and with good stirring treated with lithium t-butoxide (5.65 g, 88.14 mMole). The precipitated product was stirred at room temperature in the reaction mixture for 1 hour to complete the reaction. The lithium 2-(1,10-phenanthrolin-2-yl)-phenolate was filtered off, washed well with diethyl ether and air-dried. Yield 21 g.

Quelle