Reaktion #1474838

Reaktionsgleichung

dichlorodimethylsilane

lithium cyclohexylamide

Hexane

→

1-chloro-N-cyclohexyl-1,1-dimethylsilanamine

Ausbeute 84.0%

Lösungsmittel

THF

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeThe THF was removed under vacuum
2. 2
   Sonstigeleaving a cloudy solution
3. 3
   Filtrationthe solids were filtered off
4. 4
   Waschenwashed with hexane
5. 5
   SonstigeThe hexane was then removed from the filtrate under vacuum
6. 6
   Sonstigeleaving a clear light yellow product

Vorschrift

In the drybox in a 250 mL flask 60.0 mL (490.89 mmol) of dichlorodimethylsilane was stirred in about 80 mL of THF. To this stirring solution 6.00 g (57.08 mmol) of lithium cyclohexylamide was added as a solid slowly and stirred overnight. The THF was removed under vacuum leaving a cloudy solution. Hexane was added to this mixture and the solids were filtered off and washed with hexane. The hexane was then removed from the filtrate under vacuum leaving a clear light yellow product weighing 9.18 g. Yield 84 percent.

Quelle