Reaktion #1467538

Reaktionsgleichung

1-chloro-4-(4-chlorobutyl)benzene

1,2-dimethyl-1H-imidazole

→

title compound

1-[4-(4-Chlorophenyl)butyl]-2,3-dimethylimidazolium chloride

Reaktionsbedingungen

Aufarbeitung

1. 1
   Sonstigethe progress of the reaction by thin-layer chromatography on silica gel (MEOH:NaCL(1M), 92:8)
2. 2
   SonstigeAt the completion of the reaction
3. 3
   Temperaturcool
4. 4
   Sonstigeto obtain an oil
5. 5
   SonstigeTriturate the oil with petroleum ether until a solid
6. 6
   Sonstigeprecipitates
7. 7
   SonstigeRecrystallize the solid from MeOH/acetone
8. 8
   Filtrationfilter
9. 9
   Sonstigedry in vacuo

Vorschrift

To 4.77 g (0.023 mole) 1-chloro-4-(4-chlorobutyl)benzene add 2.23 g (0.023 mole) 1,2-dimethyl-1H-imidazole. Stir the solution for three hours at about 115° C. Follow the progress of the reaction by thin-layer chromatography on silica gel (MEOH:NaCL(1M), 92:8). At the completion of the reaction, cool to obtain an oil. Triturate the oil with petroleum ether until a solid precipitates. Recrystallize the solid from MeOH/acetone; filter and dry in vacuo to yield the title compound as a monohydrate.

Quelle