Reaktion #1368819

ord-7e7e72a6968d44bc85ccbf947acccd52

Reaktionsgleichung

C1=CC2CCC1C2
norbornylene
O=C1C=CC(=O)O1
maleic anhydride
CC(C)(C#N)N=NC(C)(C)C#N
AIBN
→
C1=CC2CCC1C2.O=C1C=CC(=O)O1
norbornene maleic anhydride

Edukte

C1=CC2CCC1C2
norbornylene
O=C1C=CC(=O)O1
maleic anhydride
CC(C)(C#N)N=NC(C)(C)C#N
AIBN

Reagenzien

Keine

Lösungsmittel

C1CCOC1
tetrahydrofuran

Reaktionsbedingungen

Temperatur
67°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    SonstigeThereafter, the polymer was precipitated
  2. 2
    Filtrationfiltered in petroleum ether/ether(1/1) solution

Vorschrift

To 50 mL of tetrahydrofuran was added 0.2M of norbornylene, 0.2M of maleic anhydride and 0.4 g of AIBN. The resulting mixture was stirred at 67° C. for 8 hours. Thereafter, the polymer was precipitated and filtered in petroleum ether/ether(1/1) solution, to obtain poly(norbornene/maleic anhydride) of Formula 1 (yield 58%).

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06455226B1uspto-grants-2002_09