Reaktion #1355609

ord-99018f67388a4025bc40fdf94c56889b

Reaktionsgleichung

$CCCCC/C=C\C/C=C\C/C=C\CCCCC(=O)OCCCCCO$

1-(z,z,z-octadeca-6,9,12-trienoyloxy)-5-hydroxypentane

$CCCCCCCC/C=C\CCCCCCCC(=O)O$

z-octadeca-9-enoic acid

$CC/C=C\C/C=C\C/C=C\C/C=C\C/C=C\CCCC(=O)O$

z,z,z,z,z-eicosa-5,8,11,14,17-pentaenoic acid

→

$CC/C=C\C/C=C\C/C=C\C/C=C\C/C=C\CCCC(=O)OCCCCCOC(=O)CCCC/C=C\C/C=C\C/C=C\CCCCC$

1-(z,z,z-octadeca-6,9,12-trienoyloxy)-5-(z,z,z,z,z-eicosa-5,8,11,14,17-pentaenoyloxy)pentane

Edukte

$CCCCC/C=C\C/C=C\C/C=C\CCCCC(=O)OCCCCCO$

1-(z,z,z-octadeca-6,9,12-trienoyloxy)-5-hydroxypentane

$CCCCCCCC/C=C\CCCCCCCC(=O)O$

z-octadeca-9-enoic acid

$CC/C=C\C/C=C\C/C=C\C/C=C\C/C=C\CCCC(=O)O$

z,z,z,z,z-eicosa-5,8,11,14,17-pentaenoic acid

Reagenzien

Keine

Reaktionsbedingungen

Detaillierte Bedingungen

See reaction.notes.procedure_details.

Vorschrift

As for Example 2, Part 2 but replacing 1-(z,z,z-octadeca-6,9,12-trienoyloxy)-3-hydroxypropane with 1-(z,z,z-octadeca-6,9,12-trienoyloxy)-5-hydroxypentane and z-octadeca-9-enoic acid with z,z,z,z,z-eicosa-5,8,11,14,17-pentaenoic acid. Chromatography yielded 1-(z,z,z-octadeca-6,9,12-trienoyloxy)-5-(z,z,z,z,z-eicosa-5,8,11,14,17-pentaenoyloxy)pentane as a pale yellow oil.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US06555700B1uspto-grants-2003_04