Reaktion #1340565

Reaktionsgleichung

CsF

toluene acetonitrile

→

desired ligands

Triphenylene

Reaktionsbedingungen

Vorschrift

1-trifluoromethanesulfonato-2-trimethylsilylbenzene (3 equivalents) is reacted with 1 equivalent of the appropriate iodoaromatic (see scheme 5a), in the presence of 5 mol % of Pd(OAc)2, 5 mol % of dppf and 4 equivalents of CsF in toluene/acetonitrile, to obtain the desired ligands of the formulae IId), IIe) and IIf).

Quelle