Reaktion #1255206

Reaktionsgleichung

Diphenyliodonium chloride

trimethyl phosphate

→

target compound

Ausbeute 81.6%

diphenyliodonium dimethylphosphonate

Ausbeute 81.6%

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.DISSOLUTIONAfter the reactants were dissolved
2. 2
   Temperaturthe mixture was cooled
3. 3
   Sonstigeto thereby yield solid matter
4. 4
   WaschenThe solid matter was washed with ether

Vorschrift

Diphenyliodonium chloride (315 mg; 1 mmol) and trimethyl phosphate (1 g) were stirred at 170° C. for 10 minutes. After the reactants were dissolved, the mixture was cooled, to thereby yield solid matter. The solid matter was washed with ether, to thereby yield 250 mg of the target compound as white crystals (yield: 81.6%). The anion content of the resultant compound was determined by ion chromatography. The chloride anion content was determined to be not greater than 10 ppm.

Quelle