Reaktion #1196

Reaktionsgleichung

10-undecenyl glycidyl ether

butyldimethylsilane

→

11-(butyldimethylsilyl)undecyl glycidyl ether

Ausbeute 82.6%

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeA 100-ml flask equipped with a stirrer
2. 2
   SonstigeThe resultant reaction mixture
3. 3
   workup.DISTILLATIONwas distilled under reduced pressure (145°-154° C./6×10-3 Torr)

Vorschrift

A 100-ml flask equipped with a stirrer was charged with 13.6 g (60 mmol) of 10-undecenyl glycidyl ether, 5.8 g (50 mmol) of butyldimethylsilane and 4 mg (0.01 mmol) of H2PtCl6. The contents were stirred at 60° C. for 24 hours. The resultant reaction mixture was distilled under reduced pressure (145°-154° C./6×10-3 Torr), thereby obtaining 14.15 g (yield: 82.6%) of 11-(butyldimethylsilyl)undecyl glycidyl ether.

Quelle