Reaktion #1178402

Reaktionsgleichung

ortho-dichlorobenzene

Acecyclone

4-biphenylacetylene

methanol

→

8-[1,1′-Biphenyl]-4-yl-7,10-diphenylfluoranthene

Reaktionsbedingungen

Aufarbeitung

1. 1
   TemperaturThe reaction was then cooled
2. 2
   FiltrationThe resulting yellow solid was filtered off
3. 3
   Waschenwashed well with methanol
4. 4
   Sonstigedried
5. 5
   Sonstigewas sublimed at 220° C.

Vorschrift

Acecyclone (12 g, 33.6 mMole) and 4-biphenylacetylene (9.0 g, 50.5 mMole) were heated to gentle reflux in ortho-dichlorobenzene (100 ML) for 2 hours. The reaction was then cooled, treated with methanol (20 mL) and stirred at room temperature for 1 hour. The resulting yellow solid was filtered off, washed well with methanol and dried. Yield of product ETM1, 17.4 g. Before use in device fabrication, ETM1 was sublimed at 220° C./10−3 mm Hg.

Quelle