Reaktion #1178393

Reaktionsgleichung

methacrylic acid

chloromethyl(2-indanyl)ether

toluene

→

(indane-2-yloxy)methyl methacrylate

Ausbeute 90.0%

Lösungsmittel

triethylamine

Reaktionsbedingungen

Aufarbeitung

1. 1
   Temperaturcooling with agitation
2. 2
   SonstigeAfter a usual aqueous work-up, the solvent was removed by distillation
3. 3
   Sonstigeto obtain a crude product
4. 4
   SonstigeIt was purified by a column chromatography

Vorschrift

Into a mixture of 103 g of methacrylic acid, 183 g of chloromethyl(2-indanyl)ether, and 1500 g of toluene was added 111 g of triethylamine under ice-cooling with agitation, and then the reaction mixture was agitated at room temperature for 16 hours. After a usual aqueous work-up, the solvent was removed by distillation to obtain a crude product. It was purified by a column chromatography to obtain 209 g of an objective product, (indane-2-yloxy)methyl methacrylate (yield 90%).

Quelle