Reaktion #11366

ord-e437a9002e724c88bacab9094317fea1

Reaktionsgleichung

CCOc1ccccc1-c1nn2c(C3CCCCCC3)nc(C)c2c(=O)[nH]1
compound
CCOc1ccccc1-c1nn2c(C3CCCCCC3)nc(C)c2c(=O)[nH]1
2-(2-Ethoxyphenyl)-5-methyl-7-cycloheptyl-3H-imidazo[5,1-f][1,2,4]-triazin-4-one
O=C(Br)CBr
bromoacetyl bromide
[Al+3].[Cl-].[Cl-].[Cl-]
aluminum trichloride
CCOc1ccc(C(=O)CBr)cc1-c1nn2c(C3CCCCCC3)nc(C)c2c(=O)[nH]1
desired product
Ausbeute 66.5%
CCOc1ccc(C(=O)CBr)cc1-c1nn2c(C3CCCCCC3)nc(C)c2c(=O)[nH]1
2-[5-(2-Bromoacetyl)-2-ethoxyphenyl]-5-methyl-7-cycloheptyl-3H-imidazo[5,1-f][1,2,4]-triazin-4-one
Ausbeute 66.5%

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

Analogously to example 57A, 1.36 g (3.7 mmol) of the compound from example 28A were reacted with 1.5 g (7.4 mmol) of bromoacetyl bromide and 1.48 g (1.1 mmol) of aluminum trichloride. Trituration with ether gave 1.2 g (66.3%) of the desired product.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07098207B2uspto-grants-2006_08