Reaktion #1102

ord-7b74a27dcc2940b5b3a704ddbd2de98d

Reaktionsgleichung

O
water
COc1c(NC2CCC(=O)CC2)ccnc1C
4-(4-oxocyclohexylamino)-3-methoxy-2-methylpyridine
NOCc1ccccc1
O-benzylhydroxylamine
CCOC(C)=O.CO
ethyl acetate methanol
O
water
COc1c(NC2CCC(=NOCc3ccccc3)CC2)ccnc1C
4-[4-(O-Benzyloximino)cyclohexylamino]-3-methoxy-2-methylpyridine

Lösungsmittel

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Vorschrift

2 g of 4-(4-oxocyclohexylamino)-3-methoxy-2-methylpyridine and 1.2 g O-benzylhydroxylamine are boiled in toluene in a water separator until liberation of water has ended. The product is isolated by column chromatography (ethyl acetate/methanol 9:1; silica gel). 1.8 g=53%

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US05723450uspto-grants-1998_03