Reaktion #1094456

Reaktionsgleichung

N1-bicyclo[2.2.1]hept-5-en-2-ylhydrazine-1-carbothioamide

2-acetylthiazole

→

title compound

4-(Bicyclo[2.2.1]hept-5-en-2-yl)-1-(thiazol-2-ylethylidene)thiosemicarbazide

Reaktionsbedingungen

Vorschrift

The title compound was prepared from a mixture of N1-bicyclo[2.2.1]hept-5-en-2-ylhydrazine-1-carbothioamide (50 mg, 0.273 mmol) and 2-acetylthiazole (41 mg, 0.33 mmol) similar to Example 3 and isolated as an off-white solid (30 mg, 37%). 1H NMR (DMSO-d6): 9.98 (s, 1H), 9.62 (s, 1H), 7.89 (m, 2H), 7.77 (m, 1H), 6.16 (ddd, J=8.1, 5.1, 2.7 Hz, 2H), 4.23 (m, 1H), 3.04 (s, 2H), 2.23 (s, 3H), 1.87-1.50 (m, 4H).

Quelle