Reaktion #1079976

Reaktionsgleichung

2-methyl-2-adamantylcyclopentadiene

acetone

pyrrolidine

→

product

Ausbeute 88.2%

3-(2-methyl-2-adamantyl)-6,6-dimethylfulvene

Ausbeute 88.2%

Lösungsmittel

methanol

Reaktionsbedingungen

Aufarbeitung

1. 1
   SonstigeThe solution formed a yellow precipitate over 96 hours which
2. 2
   Filtrationwas collected by suction filtration
3. 3
   Waschenrinsed with 50 mL methanol
4. 4
   SonstigeThe material was dried in vacuo

Vorschrift

A flask containing 19.45 grams (90.74 mmol) of 2-methyl-2-adamantylcyclopentadiene was charged with 30 mL acetone, 100 mL methanol, and 10 mL pyrrolidine (120 mmol). The solution formed a yellow precipitate over 96 hours which was collected by suction filtration and rinsed with 50 mL methanol. The material was dried in vacuo to provide 20.36 grams of product as a yellow powder (88.2%).

Quelle