Reaktion #10578

ord-32423f84d6c1444db24b353eaff2d0d9

Reaktionsgleichung

C=Cc1ccccc1
styrene
C=CC#N
acrylonitrile
O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2]
tricalciumphosphate
CC(C)(C#N)N=NC(C)(C)C#N
azobisisobutylonitrile
→
C=CC#N.C=Cc1ccccc1
Styrene-acrylonitrile copolymer

Edukte

—
resultant solution
C=Cc1ccccc1
styrene
C=CC#N
acrylonitrile
—
mercaptan
O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2]
tricalciumphosphate
CC(C)(C#N)N=NC(C)(C)C#N
azobisisobutylonitrile

Reagenzien

Keine

Lösungsmittel

O
water

Reaktionsbedingungen

Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    workup.ADDITIONwere added
  2. 2
    WaschenThe resultant was washed
  3. 3
    Sonstigedried

Vorschrift

71 parts of styrene, 29 parts of acrylonitrile, 120 parts of deionized water and 0.2 parts of azobisisobutylonitrile (AIBN) were blended. To the blend, 0.5 parts of tricalciumphosphate and 0.3 parts of mercaptan-containing chain transfer agent were added. The resultant solution was heated to 80° C. for 90 minutes and kept for 180 minutes. The resultant was washed, dehydrated and dried. Styrene-acrylonitrile copolymer (SAN) was obtained.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07094818B2uspto-grants-2006_08