Reaktion #1013623

Reaktionsgleichung

aluminum chloride

cyclohexyl chloride

→

tricyclohexylbenzene

Ausbeute 50.7%

Lösungsmittel

benzene

Reaktionsbedingungen

Aufarbeitung

1. 1
   workup.ADDITIONAfter the dropwise addition
2. 2
   workup.STIRRINGthe mixture was stirred at room temperature for 5 hours
3. 3
   ExtraktionThe organic layer was extracted with ethyl acetate
4. 4
   workup.DISTILLATIONthe obtained organic layer was distilled off under reduced pressure at 40° C
5. 5
   workup.DISTILLATIONAfter further distillation off under reduced pressure at 170° C.
6. 6
   Temperaturthe product was cooled to room temperature
7. 7
   workup.ADDITIONcharged into 50 ml of acetone
8. 8
   Sonstigerecrystallized
9. 9
   SonstigeThe crystal precipitated
10. 10
    Filtrationwas collected by filtration

Vorschrift

6.83 g of aluminum chloride was added to 20.0 g of benzene, followed by cooling/stirring at 3° C., and 40.4 g of cyclohexyl chloride was slowly added dropwise. After the dropwise addition, the mixture was stirred at room temperature for 5 hours and poured into ice water. The organic layer was extracted with ethyl acetate, and the obtained organic layer was distilled off under reduced pressure at 40° C. After further distillation off under reduced pressure at 170° C., the product was cooled to room temperature, charged into 50 ml of acetone and thereby recrystallized. The crystal precipitated was collected by filtration to obtain 14 g of tricyclohexylbenzene.

Quelle