Reaktion #1003384

ord-d70f62c24e994e02984489792aae06a3

Reaktionsgleichung

C[SiH](O[Si](C)(C)C)O[Si](C)(C)C
1,1,1,3,5,5,5-heptamethyltrisiloxane
OO
hydrogen peroxide
C=CCOCC(C)O
1-allyloxy-2-propanol
[Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-]
magnesium silicate
→
CCC(O)OCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C
[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl]propoxy]-propanol

Edukte

C[SiH](O[Si](C)(C)C)O[Si](C)(C)C
1,1,1,3,5,5,5-heptamethyltrisiloxane
OO
hydrogen peroxide
—
solution
C=CCOCC(C)O
1-allyloxy-2-propanol
[Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-]
magnesium silicate

Reagenzien

[Cl][Pt-2]([Cl])([Cl])([Cl])([Cl])[Cl].[H+].[H+]
chloroplatinic acid
[Pt]
platinum

Lösungsmittel

CO
carbinol
CC(C)O
isopropanol

Reaktionsbedingungen

Temperatur
80°CELSIUS
Detaillierte Bedingungen
See reaction.notes.procedure_details.

Aufarbeitung

  1. 1
    FiltrationFiltration

Vorschrift

A carbinol functional siloxane having Structure VIII was prepared by hydrosilylation. Specifically, 1.2 parts by weight of 1-allyloxy-2-propanol in the presence of a catalytic amount of chloroplatinic acid (10 ppm platinum as a solution of 7.5% by weight in isopropanol) and 0.004 parts by weight of magnesium silicate was warmed to 80° C. under inert atmosphere. One part by weight 1,1,1,3,5,5,5-heptamethyltrisiloxane was added through an addition funnel over 5 hours. The mixture was treated with 0.02 parts by weight of a 35% solution of aqueous hydrogen peroxide and stirred for two hours at 80° C. Filtration yields [3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl]propoxy]-propanol (CAS# [77623-99-5]) as a water white liquid.

Quelle

DOI: 10.6084/m9.figshare.5104873.v1Patent: US07268176B2uspto-grants-2007_09